Vinyl Cyclohexene Reaction

Other metabolites were 4 vinyl 1 2 epoxycyclohexane 4 vinyl 1 cyclohexene dioxide.

Vinyl cyclohexene reaction.

10 17 2016 en english us sds id. It is a colorless liquid. Properties 4 vinyl 1 cyclohexene diepoxide is a colorless liquid at room temper ature ntp 1989. 4 vinylcyclohexene is an organic compound consisting of a vinyl group attached to the 4 position of the cyclohexene ring.

The main 4 vinyl 1 cyclohexene metabolite formed in mice liver microsomes after incubation was 4 vinylcyclohexane 1 2 diol. It is a precursor to vinylcyclohexene dioxide. Benzene is converted to cyclohexylbenzene by acid catalyzed alkylation with cyclohexene. 4 vinyl 1 cyclohexene stabilized revision date 18 jan 2018 decomposition temperature no information available viscosity 0 7 mpa s at 20 c molecular formula c8 h12 molecular weight 108 18 10.

Journal of analytical and applied pyrolysis 1988 13 4 259 275. Use of the information documents and data from the echa website is subject to the terms and conditions of this legal notice and subject to other binding limitations provided for under applicable law the information documents and data made available on the echa website may be reproduced distributed and or used totally or in part for non commercial purposes provided that echa is. Take off immediately all contaminated clothing. They polymerize in the presence of catalysts or when heated.

Epoxides are highly reactive. 4 vinylcyclohexene undergoes a retro diels alder reaction to butadiene with log k 15 2 62000 2 3rt 124 or 15 7 61 800 2 3rt. 125 at lower temperatures optically active 4 exo dideuteriovinyl cyclohexene undergoes both racemization and deuterium scrambling to c 3. Stability and reactivity reactive hazard none known based on information available stability stable under normal conditions.

Cyclohexylbenzene is a precursor to both phenol and cyclohexanone. Enev4520 2 8 p273 avoid release to the environment p303 p361 p353 if on skin or hair. Conditions to avoid excess heat. Physical and chemical properties of 4 vinyl 1 cyclohexene diepoxide are listed in the following table.

Although chiral it is used mainly as the racemate. 4 vinyl 1 cyclohexene dioxide increased approx 10 times the forward mutation rate of v79 chinese hamster cells. Rearrangement reactions in the thermal formation of aromatics from cycloolefins. 1 vinyl 3 cyclohexene dioxide reacts with active hydrogen compounds such as alcohols and amines.

These polymerization reactions can be violent. It is soluble in water. Cyclohexene is produced by the partial hydrogenation of benzene a process developed by the asahi chemical company. Compounds in this group react with acids bases and oxidizing and reducing agents.

However it slowly hydrolyzes in aqueous solutions akron 2009.